The Hatrurim Formation or ''Mottled Zone'' is a

geologic formation A geological formation, or simply formation, is a body of rock having a consistent set of physical characteristics ( lithology) that distinguishes it from adjacent bodies of rock, and which occupies a particular position in the layers of rock exp ...

with outcrops all around the

Dead Sea Basin Death is the irreversible cessation of all biological functions that sustain an organism. For organisms with a brain, death can also be defined as the irreversible cessation of functioning of the whole brain, including brainstem, and brain ...

: in the

Negev Desert The Negev or Negeb (; he, הַנֶּגֶב, hanNegév; ar, ٱلنَّقَب, an-Naqab) is a desert and semidesert region of southern Israel. The region's largest city and administrative capital is Beersheba (pop. ), in the north. At its southe ...

Israel Israel (; he, יִשְׂרָאֵל, ; ar, إِسْرَائِيل, ), officially the State of Israel ( he, מְדִינַת יִשְׂרָאֵל, label=none, translit=Medīnat Yīsrāʾēl; ), is a country in Western Asia. It is situated ...

, in the

Judaean Desert The Judaean Desert or Judean Desert ( he, מִדְבַּר יְהוּדָה, Midbar Yehuda}, both ''Desert of Judah'' or ''Judaean Desert''; ar, صحراء يهودا, Sahraa' Yahuda) is a desert in Palestine and Israel that lies east of Jerusa ...

on the

West Bank The West Bank ( ar, الضفة الغربية, translit=aḍ-Ḍiffah al-Ġarbiyyah; he, הגדה המערבית, translit=HaGadah HaMaʽaravit, also referred to by some Israelis as ) is a landlocked territory near the coast of the Mediter ...

, and in western

Jordan Jordan ( ar, الأردن; tr. ' ), officially the Hashemite Kingdom of Jordan,; tr. ' is a country in Western Asia. It is situated at the crossroads of Asia, Africa, and Europe, within the Levant region, on the East Bank of the Jordan Rive ...

. It includes late

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...

Eocene The Eocene ( ) Epoch is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (mya). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene' ...

aged impure

limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...

along with

coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...

bearing

chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...

and

marl Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part o ...

. The rocks have been subjected to pyrometamorphism resulting from combustion of contained or underlying coal or

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...

deposits. The formation is named for exposures in the Hatrurim Basin which lies west of the

Dead Sea The Dead Sea ( he, יַם הַמֶּלַח, ''Yam hamMelaḥ''; ar, اَلْبَحْرُ الْمَيْتُ, ''Āl-Baḥrū l-Maytū''), also known by other names, is a salt lake bordered by Jordan to the east and Israel and the West Bank ...

.Mindat location
/ref> During the 1960s, a group of scientists from the

Hebrew University of Jerusalem The Hebrew University of Jerusalem (HUJI; he, הַאוּנִיבֶרְסִיטָה הַעִבְרִית בִּירוּשָׁלַיִם) is a public research university based in Jerusalem, Israel. Co-founded by Albert Einstein and Dr. Chaim Weiz ...

, including

Yaakov Ben-Tor Yaakov Ben-Tor ( he, יעקב בן-תור; 1910–2002) was an Israeli geologist. Biography Ben-Tor was born as Kurt Winter in the Baltic city of Königsberg, East Prussia, Germany, (since 1945 Kaliningrad, now in Russia) in 1910. Winter began ...

, and Lisa Heller-Kallai, discovered that the Hatrurim Formation contained several rare, if not unique, mineral assemblages. The formation is the type locality for five unusual minerals and noted for other minerals serving as reference for mineral phases formed at high temperature in the clinker of

Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th c ...

Shulamit Gross Shulamit Gross (Hebrew: שולמית גרוס; lived 1 October 1923 – 19 Sep 2012) was an Israeli mineralogist and geologist who studied the Hatrurim Formation. Biography Gross was born as Shulamit Lifszyc in Grodno, Poland (today, Hrodna, B ...

, an Israeli geologist and mineralogist, continued to study these rare minerals. In 1977, she published a monograph describing 123 mineral species discovered in the Hatrurim Formation. Five were previously known only from a single locality, and eight others were known only as artificial products of the cement industry. Gross also discovered several minerals completely new to science:

bentorite Bentorite is a mineral with the chemical formula Ca6(Cr,Al)2(SO4)3(OH)12·26H2O. It is colored violet to light violet. Its crystals are hexagonal to dihexagonal dipyramidal. It is transparent and has vitreous luster. It has perfect cleavage. It ...

ye'elimite Ye'elimite is the naturally occurring form of anhydrous calcium sulfoaluminate, . It gets its name from Har Ye'elim in Israel in the Hatrurim Basin west of the Dead Sea where it was first found in nature by Shulamit Gross, an Israeli mineralogi ...

, and hatrurite. A fourth mineral discovered by Gross was only described later by Dietmar Weber and Adolf Bischoff, which they named

grossite Grossite is a calcium aluminium oxide mineral with formula CaAl4O7. It is a colorless to white vitreous mineral which crystallizes in the monoclinic crystal system. Grossite was first described 1994 for an occurrence in the Hatrurim Formation of ...

after Shulamit. Gross demonstrated that the unique mineral assemblages discovered in the Hatrurim Formation were formed by pyrometamorphism, and she managed to recreate in the laboratory most of the minerals by heating the precursor sedimentary rocks of the Ghareb and Taqiye formations. In 2011, a new

perovskite Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as ...

-related mineral from the Hatrurim Basin was named shulamitite to honor Shulamit Gross for her works. Shulamitite, ideally , is a mineral intermediate between

() and

brownmillerite Brownmillerite is a rare oxide mineral with chemical formula . It is named for Lorrin Thomas Brownmiller (1902–1990), chief chemist of the Alpha Portland Cement Company, Easton, Pennsylvania. Discovery and occurrence The chemical compound ...

(), a mineral of the

cement clinker 200px, Typical clinker nodules 200px, Hot clinker Cement clinker is a solid material produced in the manufacture of Portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually to in diameter. It is produced by sinte ...

References

Geologic formations of Israel Geologic formations of Jordan Dead Sea basin {{geologic-formation-stub